Before the good doctor penned the three laws of robotics, there was an awful lot of Frankenstinia in robot stories; the assumption that they would turn on mankind, either directly, or by rendering them obsolete (there's still an element of the latter surfacing from time to time). For cyborgs (historical) apart from the six million dollar man) try Pohl's "Man plus" or McCaffrey's "The Ship that sang" (of course Helga's a cyborg; where did you get the idea they had to be humanoid?)
Classical automatones go back to Greek myth, and, unlike Asimov's pacifistic creations, were often built for warfare (the ancient Greeks had possibly a clearer idea than Dr Asimov as to where research budgets were most healthy). However, I'm not certain they can be classified as science fiction, any more than the eastern european golems (direct ancestors of Capek's Universal Robots or workers).
The Artificial intelligence that turns them into more than just preprogrammed automated lathes? perhaps Harry Harrison/Marvin Minsy's "The Turing option".
Androids have, over the decades, been anything from humanoid robots, the only difference between them and their "designed to a purpose" bretheren being cosmetic, through synthetic life forms to beings genetically identical to humans, born from synthetic wombs. Most of the characters in Huxley's "Brave new world" would qualify for this definition, as well as Cherryh's azi (Cyteen, forty thousand in Gehenna).
