You rang, outan?
For a molecule to leave its gravity well (which might be a planet, a moon, a comet or even a star) it must achieve escape velocity (a misnomer; it is speed, a scalar quantity, that counts, not the vector direction with velocity).
The average momentum(I can't remember which curve defines the probabilities of so much faster and so much slower in the speed distribution) of a molecule at a particular temperature is constant, so the speed it is travelling is the inverse of its mass. Is that clear? I hate to use the freeway analogy, with trucks, automobiles and bikes, as this involves several thousand collisions per second, which is worse even than LA.
Venus' atmosphere contains lots of heavyweight molecules, like formaldehyde, sulphuric acid and various long-chain hydrocarbons which would be liquids or even solids on any reasonable planet (if you succeeded in cooling the place down you probably wouldn't need to bituminise the roads and parking lots; the entire surface would already be black). Any lightweight molecules, like hydrogen and helium, have long since gone exploring the cosmos, and any captured solar wind had better find something to compound with pretty fast, or it'll be on its way in a matter of decades. Medium weight molecules, like oxygen or water, coming from breakdown of the larger lumps by actinic sunlight have their emigration papers, too. Perelandra is no place to plan a beach holidy.
Personally, without a worthwhile magnetic field (which Venus lacks) I don't see the ionised layer of the atmosphere stopping much egress. Oh, the sunlight itself will dissociate many atoms, and the solar wind itself is largely ionised, but unlike Earth, where the path of such charged objects is curved by magnetism, half of the ions will be given extra speed by electrostatic repulsion, balancing those who are attracted. Net gain, not enough to worry about.
So an atmosphere on a low gravity world, even quite a warm one, would be quite possible; breathing it might be a bit problematic. Particularly water vapour would diappear about twice as fast as oxygen. Inconvenient, in the long run.