My granddaughter counted to two yesterday (and I mean by that, that she actually understood the meaning, as she picked out two bottles, rather than just saying the "words" 'one, two, three' by rote.) We have a lot of binary things on the body - feet, shoes, socks, legs, knees, arms, shoulders, hands, mittens, eyes, ears, lips... but binary numbers become very long and unmanageable, very quickly and it is quite easy to see why we never used them for notation.
I agree with the previous posts though, a hexadecimal or duodecimal system, one which was based upon a number that is divisible in several different ways, would be much more useful. i.e. 10 is divisible by only 1,2 and 5. 16 is divisible by 1,2,4, and 8. But 12 is divisible by 1,2,3,4 and 6.
That such a small number is so easily divided in different ways explains why the dozen was used for baking, manufacturing and sales, rather than 10.